Designing Material Properties from Molecular Principles Targeted design of electronic and magnetic properties in novel materials remains a critical bottleneck in the development of many next-generation electrical and electrochemical devices. In this talk, I will describe how the principles of molecular inorganic chemistry can be applied to systematically engineer materials hosting a diverse range of desired properties. Type of Event: Departmental Colloquium Materials Chemistry and Nanoscience Seminar Read more about Designing Material Properties from Molecular Principles
From Rare-Earth Extraction to Polymer Recycling: Innovations in Materials for Sustainability The transition to a sustainable future requires innovative approaches in materials design, utilization, and recycling. In this talk, I will discuss two advancements at the intersection of polymer chemistry and sustainability: the development of metal-chelating polymers for rare-earth element (REE: La–Lu, Y, and Sc) extraction, and the synthesis of chemically recyclable polymers. Type of Event: Departmental Colloquium Materials Chemistry and Nanoscience Seminar Read more about From Rare-Earth Extraction to Polymer Recycling: Innovations in Materials for Sustainability
Hierarchical Molecular Design at Organic-Inorganic Hybrid Lattices The pursuit of next-generation materials to address the energy and sustainability crisis hinges on hybrid crystalline systems, particularly layered lattices with well-defined organic-inorganic interfaces. These materials harness the vast chemical space of organics and the superior electronic, photonic, or catalytic performance of inorganics, making the assembly tunable and solution processable. Type of Event: Departmental Colloquium Materials Chemistry and Nanoscience Seminar Read more about Hierarchical Molecular Design at Organic-Inorganic Hybrid Lattices
Fundamental Mechanisms in Sustainable Materials from Global Environment to Climate Change Climate change and global air pollution are the world’s two most serious issues. Negative carbon and polluted air capture are critical strategies for addressing rising CO2 and air pollution levels. State-of-the-art materials design at the atomic level is in high demand, and their fundamental mechanism must be revealed using cutting-edge microscopic and spectroscopic methodologies. As a result, the utilization of sustainable materials (e.g. Type of Event: Departmental Colloquium Materials Chemistry and Nanoscience Seminar Read more about Fundamental Mechanisms in Sustainable Materials from Global Environment to Climate Change
Synthesis and Structure-Property Characterization of Lignin-Derived Thermoplastic Poly(ether ester)s Semi-aromatic polyesters derived from petroleum are an important class of polymers that encompass a wide variety of thermal and mechanical properties. Unfortunately, replacing the aromatic component with cost-competitive bioderived monomers is an ongoing challenge. In this presentation, we describe the synthesis of nine different polyesters made from AB monomers that can be derived from lignin, and include full characterization of their thermal, mechanical, and rheological properties. Type of Event: Materials Chemistry and Nanoscience Seminar Read more about Synthesis and Structure-Property Characterization of Lignin-Derived Thermoplastic Poly(ether ester)s
Recent Approaches to 2D and 3D Materials for Second Harmonic Generation The second harmonic generation (SHG) is a nonlinear coherent second-order scattering process that causes frequency doubling of incident light. It is widely used in laser technology, spectroscopy, microscopy, wireless communication technology and fiber-optic communication systems. The main requirement for the SHG process is the noncentrosymmetry of the material, since the second-order susceptibility coefficient, which is responsible for the second harmonic generation, is zero in all centrosymmetric structures. Type of Event: Materials Chemistry and Nanoscience Seminar Read more about Recent Approaches to 2D and 3D Materials for Second Harmonic Generation
Multifunctional Hydrogels for Wound Healing Zoom link for seminar: https://zoom.us/j/92955070680 Type of Event: Materials Chemistry and Nanoscience Seminar Read more about Multifunctional Hydrogels for Wound Healing
Convergent Ab Initio Analysis of the Multi-Channel HOBr + H Reaction High-level potential energy surfaces for three reactions of hypobromous acid with atomic hydrogen were computed at the CCSDTQ/CBS//CCSDT(Q)/complete basis set level of theory. Focal point analysis was utilized to extrapolate energies and gradients for energetics and optimizations, respectively. The H attack at Br and subsequent Br–O cleavage were found to proceed barrierlessly. The slightly submerged transition state lies −0.2 kcal mol−1 lower in energy than the reactants and produces OH and HBr. Type of Event: Physical Seminar Read more about Convergent Ab Initio Analysis of the Multi-Channel HOBr + H Reaction
Formation and Dissociation of Hydrocarbons Under Interstellar Conditions Hydrocarbons of all shapes and sizes are found throughout the various stages of star- and planet formation. Recently, using radio astronomical observations, a variety of cyclic- and even polycyclic hydrocarbons have been detected in the very cold (10 K) Taurus molecular cloud. These detections challenge our understanding of the chemical formation mechanisms under these low-temperature and low-density conditions. Type of Event: Physical Seminar Read more about Formation and Dissociation of Hydrocarbons Under Interstellar Conditions
Plasma-Assisted Catalysis for Ammonia Synthesis Ammonia (NH3) is important in the production of many products including fertilizers, plastics, resins, synthetic fabrics, and explosives. At the industrial scale, NH3 is produced using the Haber–Bosch (H–B) process, which is typically carried out at high temperatures and pressures. This process produces over 300 million metric tons of carbon dioxide each year, and consumes 1-2% of the world’s energy supply. Type of Event: Physical Seminar Read more about Plasma-Assisted Catalysis for Ammonia Synthesis