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Slideshow

Improving the Stability of Perovskite Solar Cells:
Recent Developments and Future Prospects

Portrait of Temitayo Oluwadara, speaker
Date & Time:
-
Location:
Davison Life Sciences Building, Room C127

Lead halide perovskite nanocrystal (PNC) materials have garnered much attention lately because of their fascinating optical and optoelectronic characteristics. These characteristics make them excellent candidates for photovoltaic applications with high power conversion efficiencies for solar cell applications. However, degradation during thermal treatment and poor stability against moisture and UV light are common problems for PNCs. Hence, for this technology to be deployed on a large scale, efficiency must be combined with long-term durability, which means there is a need to improve the stability of PNC materials to enhance their applicability. To meet this challenge, techniques to increase stability, like adjusting the perovskite's composition, adding hydrophobic coatings, exchanging metal electrodes for carbon or transparent conducting oxides, and packaging, have been investigated and employed. Furthermore, moisture and oxygen are known to be some of the most pervasive external factors that lead to the degradation of PNCs. This seminar, therefore, focuses on how polymeric materials have been used as hydrophobic protection against environmental moisture while simultaneously maintaining or improving the principal properties of PNCs. 

References

  1. Juanita Hidalgo, Waldemar Kaiser, Yu An, Ruipeng Li, Zion Oh, Andrés-Felipe Castro-Méndez, Diana K. LaFollette, Sanggyun Kim, Barry Lai, Joachim Breternitz, Susan Schorr, Carlo A. R. Perini, Edoardo Mosconi, Filippo De Angelis, and Juan-Pablo Correa-Baena. (2023). Synergistic Role of Water and Oxygen Leads to Degradation in Formamidinium-Based Halide Perovskites Journal of the American Chemical Society , 145 (45), 24549-24557 DOI: 10.1021/jacs.3c05657
  2. Jiang, G., Guhrenz, C., Kirch, A., Sonntag, L., Bauer, C., Fan, X., Wang, J., Reineke, S., Gaponik, N., & Eychmüller, A. (2019). Highly luminescent and water-resistant CsPbBr3-CsPb2Br5 perovskite nanocrystals coordinated with partially hydrolyzed poly(methyl methacrylate) and polyethylenimine. ACS Nano, 13(9), 10386–10396. https://doi.org/10.1021/acsnano.9b04179
  3. Carrizo, A. F., Belmonte, G. K., Santos, F. S., Backes, C. W., B Strapasson, G., Schmidt, L. C., Rodembusch, F. S., & Weibel, D. E. (2021). Highly water-stable polymer-perovskite nanocomposites. ACS Applied Materials & Interfaces, 13(49), 59252–59262. https://doi.org/10.1021/acsami.1c17594
  4. Jin, X., Ma, K., Chakkamalayath, J., Morsby, J., & Gao, H. (2022). In situ photocatalyzed polymerization to stabilize perovskite nanocrystals in protic solvents. ACS Energy Letters, 7(2), 610–616 https://doi.org/10.1021/acsenergylett.1c02660
Temitayo Oluwadara
Department:
Graduate Student, Department of Chemistry
University of Georgia

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