Tags: Materials Chemistry and Nanoscience Seminar

Polyhydroxyalkanoates, a class of biodegradable polyester made by fermentation, are explored via extrusion with various additives for the goal of improving mechanical properties. Two types of PHA are used, poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) with 6% hexanoate and 8% hexanoate, to understand how copolymer ratios affect properties. The two PHAs undergo blending and reactive extrusion with additives such as radical peroxide initiator, PLA…
Synthesis of complex solids is often a bottleneck of the materials by design concept. The limitations of conventional synthetic approaches resulted in inability to synthesize predicted materials in ternary and quaternary systems with drastically different reactivities of the constituent elements. Several strategies to advance synthesis and produce challenging phases will be discussed, such as averaging precursor reactivity by atomic mixing of…
Chemical Vapor Transport (CVT) is a useful synthetic method for low-dimensional nanomaterials. This seminar will discuss how we’ve used it to achieve high-quality 1-D and 2-D material synthesis at high yields and larger scales than previously reported for transition metal chalcogenides and transition metal chalcohalides, and how CVT has been used for the controlled growth of several uranium and thorium chalcogenides. With polymorph control…
Creating and curating new data appends the way we approach materials science. In additive manufacturing (AM), the fabrication of parts and objects with high complexity and high performance is advantageous over other methods. Using nanocomposites enables highly improved properties even with “commodity polymers” that do not need to undergo high-temperature processes or extensive reformulation. With artificial intelligence and machine learning (AI/…
Developing catalysis platforms for efficient chemical transformations requires either building upon useful empirical evidence or studying unexplored design spaces. Importantly, both approaches benefit from merging different research fields to solve new challenges. Here, I will discuss how materials design parameters can be applied to molecular electrocatalysts in the form of porous supramolecules to mimic confined enzyme/nanomaterial catalysis.…
At the nanoscale, magnetic, optical, electronic, and thermal processes can differ drastically from their bulk counterparts. These deviations stem from reduced crystalline domains, large surface areas, and quantum confinement, leading to physical and chemical properties intricately dependent on size, morphology, and ligand identity as opposed to purely compositional structure. This remarkable tunability, combined with their solution…