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Slideshow

Tags: Inorganic Seminar

Of the three most common Fe-S clusters found in nature, the [4Fe-4S] cluster is the most abundant and accounts for the most diverse functions, ranging from electron transfer to regulation of gene expression and radical generation1. Solvent accessible [4Fe-4S] clusters are very sensitive to oxidative degradation and as such, are sometimes used as sensors of oxidative stress2. The major aim of this research project is to understand the mechanism…
Cyclic polymers do not contain end groups, and as a result they demonstrate a number of unique physical properties. For example, the density, refractive index, Tg, viscoelasticity, reptation, and surface properties of cyclic polymers all differ from those of their more common linear analogs. Over the past fifty years a handful of catalysts have been discovered that can create cyclic polymers. In this seminar, four new catalysts will be presented…
Energy density and cost of Li-ion batteries (LIBs) based on conventional intercalation compounds are closely approaching their limits. The reliance of conventional cathodes on the use of toxic metals additionally endangers health and safety of miners in developing countries. Conversion-type active materials offer an opportunity to double energy stored in LIBs, reduce their cost by the same factor, and improve cell safety. These materials may be…
The principal goal of the La Pierre group synthetic and X-ray absorption spectroscopic (XAS) studies is to disentangle the complex electronic structure of f-block materials. Definitive spectroscopic and thermodynamic signatures of electronic structure phenomena unique to lanthanide, actinide, and transuranic materials are lacking. In particular, the process of establishing clear correspondence between spectroscopic signature, electronic…
Bimetallic nanocrystals, made of two different metal species, have properties that are often superior to their single-metal counterparts. The arrangement of the two different metals relative to each other in the nanocrystal is very important in determining the nanocrystal properties, and considerable effort has been made to deposit one metal atop the nanocrystal surface of another metal with precision in location. It remains a grand challenge to…
Freestanding nanosheets of lead titanate (PbTiO3) were synthesized via a hydrothermal approach. PbTiO3 is distinguished for being a piezoelectric material that exhibits ferroelectricity, as well as for having a high Curie temperature compared to other perovskite materials. For this reason, research on PbTiO3 nanomaterials is of great interest for applications involving high temperature piezoelectric ceramics and microelectronics. The isolation…
Cancer is a fatal disease, affecting approximately 25% of the population worldwide1. Given the global impact, early detection of cancer is needed to reduce morbidity and prevent mortality2. Unfortunately, not all forms of cancer diagnosis such as blood tests or biopsy can detect the disease during its early stages. Medical imaging has emerged as one of the salient tools for early detection, but not all imaging modalities fit this criterion. Some…
Approximately two-thirds of the energy utilized globally is lost as heat in the atmosphere.1 The role of thermoelectric materials is gaining more attention to recycle this lost energy, especially in light of the increased worldwide projection for energy demand. Unfortunately, the conversion efficiency of thermoelectric applications averages around 5-10%, which raises concern regarding the ability to expand these applications on a wider scale.2…
My talk will cover work on two projects. One project focuses on the development of new Mn coordination complexes as a replacement for commercially available MRI contrast agents, which are all gadolinium-based. This work is driven by a high-state of anxiety surrounding well-established and newly emergent toxicity concerns related to Gd-based contrast agents. The other project is focused on developing redox active Mn coordination complexes as…

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