Aerosol Chemistry, Mass Spectrometry

The Smith group studies the chemistry of aerosol particles that are important in the atmosphere. In particular, we are learning about how organic aerosols react with oxidants such as OH, O3, NO3 and Cl. By characterizing the chemical composition of reacted particles using mass spectrometry we can determine how fast a gas-particle reaction occurs, which products are formed and their yields. This information helps us to understand how organic aerosols are transformed chemically during their lifetimes in the atmosphere and helps us to predict how they will grow, take up water and scatter sunlight. To obtain the detailed chemical information necessary for these experiments, we use an Aerosol CIMS (chemical ionization mass spectrometer) developed in this lab.

Publications

Zhao, Z.; Husainy, S.; Stoudemayer, C. T.; Smith, G. D. Reactive uptake of NO3 radicals by unsaturated fatty acid particles. Physical Chemistry Chemical Physics 2011, 13(39), 17809. Abstract
Renbaum, L. H.; Smith, G. D. Artifacts in measuring aerosol uptake kinetics: the roles of time, concentration and adsorption. Atmospheric Chemistry and Physics Discussions 2011, 11(3), 7971-8002. Abstract
Zhao, Z.; Husainy, S.; Smith, G. D. Kinetics Studies of the Gas-Phase Reactions of NO 3 Radicals with Series of 1-Alkenes, Dienes, Cycloalkenes, Alkenols, and Alkenals. The Journal of Physical Chemistry A 2011, 115(44), 12161-12172. Abstract
Renbaum, L.; Smith, G. Organic nitrate formation in the radical-initiated oxidation of model aerosol particles in the presence of NOx. Physical Chemistry Chemical Physics 2009, 11, 8040-8047. Abstract
Hearn, J.; Smith, G. Ozonolysis of mixed oleic acid/n-docosane particles: The roles of phase, morphology, and metastable states. Journal of Physical Chemistry A 2007, 111, 11059-11065. Abstract